Glass Transition Temperature Database

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Polymer Tg (K) Reference
Poly(CL49-co-TOSUO4) 213 10.1021/ma061654g
Poly(CL74-co-OPD8) 216.4 10.1021/ma061654g
Poly(CL49-co-OPD4) 216 10.1021/ma061654g
Poly(butyl acrylate-co-methyl methacrylate ) 277 10.1021/ma070853c
Poly(2-isopropyl-2-oxazoline)s 300 10.1021/ma900838v
polylactide 330 10.1021/ma301484u
poly(butyl methacrylate ) 293 10.1021/acs.macromol.5b00299
Poly[vinylphenol-b-2-(dimethylamino)ethyl methacrylate ] Diblock 457 10.1021/ma801546z
α,ω-Dimercapto-poly(cis-1,4-isoprene) 214 10.1021/ma200738b
polylactide ~ 313 10.1021/ma0704360
Polyimide 555.7 10.1021/ma901251y
PS-b-PFAMS Copolymers 4 377 10.1021/ma201526w
poly(rac-methylcyclohexylglycolide) 346 10.1021/ma071430d
poly(VDF-co-TFP) and poly(TrFE-co-TFP) 284 10.1021/acs.macromol.5b01964
poly(BzA-co-IBVE) 279 10.1021/ma902840d
poly(9,9-dioctylfluorene) 348 10.1021/ma0612273
polyethylene oxide 331 10.1021/ma900690e
poly(2,2′-dioxy-1,1′-biphenyl)phosphazene 433 10.1021/ma8015568
Polylactide 192 10.1021/ma101155p
Poly(ferrocenyldimethylsilane-b-methyl methacrylate ) 333 10.1021/ma052521i
poly(thieno[3,4-b]pyrazine)s 333 10.1021/ma801057s
polystyrene ~ 373 10.1021/acs.macromol.5b02326
Poly(styrene-b-isobutylene-b-styrene) 373 10.1021/ma051958n
Poly(ε-caprolactone) 213 10.1021/ma802618h
poly(ε-caprolactone) 324 10.1021/ma101945f
Poly(phenylacetylene) 324 10.1021/ma0527597
Thermoset Polyimide 153 10.1021/acs.macromol.5b00654
Poly(dimethylsiloxane) 148 10.1021/ma052275a
polyethylene 394 10.1021/ma0627774
Polystyrene 305 10.1021/ma070378i
poly(pentadecalactone) 246 10.1021/ma702419m
polybenzoxazine 623 10.1021/ma3004218
poly(hexyl methacrylate ) 253 10.1021/ma401536r
poly(butyl methacrylate ) 300 10.1021/ma401536r
poly(thiocarbonate)s 315 10.1021/acs.macromol.6b00272
Poly[4-(1-adamantyl)styrene] 505 10.1021/ma7028743
poly(styrene)−poly(butadiene)−poly(styrene) 373 10.1021/ma061703p
poly(9,9-dioctylfluorene) 348 10.1021/ma902138g
polyamides 511 10.1021/ma051827m
Linear Poly(N-isopropylacrylamide) 305 10.1021/ma0614545
poly(ethylene glycol vinyl ether phosphotriester ) 234 10.1021/ma402480a
poly(2-oxazoline)s 249.6 10.1021/ma9020455
Poly(MCP-alt-MMI) 393 10.1021/ma4020092
Poly(MCP-alt-BMI) 339 10.1021/ma4020092
Poly(MCP-alt-CHMI) 415 10.1021/ma4020092
Hydrogenated Poly(MCP-alt-PhMI) 422 10.1021/ma4020092
Poly(MCP-alt-PhMI) 432 10.1021/ma4020092
poly(caprolactone-co-trimethylene carbonate)−poly(ethylene glycol)−poly(caprolactone-co-trimethylene carbonate ) 432 10.1021/ma800562s
poly(ε-caprolactone) 332.2 10.1021/ma9011076
poly[(R)-3-hydroxybutyrate] 277 10.1021/ma060908v
poly(aPP-NB)_74 264 10.1021/acs.macromol.5b01153
poly(9,9-di-n-octyl-2,7-fluorene) 335 10.1021/ma801177h
Poly(α-methylene-ε-caprolactone-co-styrene) 356 10.1021/ma0527146
3,5-Diallyl-Terminated Poly(quinoxaline − ether − ketone ) 360 10.1021/ma0526589
copolyfluorenes 360 10.1021/ma9004617
atactic polystyrene 368.22 10.1021/ma061159k
polyacrylonitrile 393 10.1021/ma901336q
polystyrene ~ 373 10.1021/ma060977%2B
Polyacrylates 332 10.1021/ma401125j
poly(p-methoxyphenyl-p'-acryloyloxy benzoate ) 338 10.1021/ma0718898
Poly-PhNDI 470 10.1021/ma062522q
Poly(n-butyl acrylate)-block-poly(acrylic acid ) ~ 208 10.1021/ma0609578
Polystyrene-b-Poly(2-(2′,3′,4′,6′-tetra-O-acetyl-β-d-galactosyloxy)ethyl methacrylate-co-styrene ~ 373 10.1021/ma9019015
Polystyrene-block-Poly(n-butyl-ran-n-hexyl) Methacrylate 294 10.1021/ma800645u
Poly(MA-VPGVG) 288 10.1021/ma070527x
polycaprolactone 373 10.1021/ma0712394
polybutadiene 174 10.1021/ma802488a
poly ( St-Fl2 ) 378 10.1021/ma900486m
Amphiphilic Poly(styrene)-block-poly(acrylic acid)-block-poly(styrene), PS-b-PAA-b-PS 353 10.1021/ma801805q
poly(St-alt-MAn) 375 10.1021/ma052520q
Polystyrene 373 10.1021/ma801742p
Poly(ethylene imine ) 220 10.1021/ma801064e
poly(methyl methacrylate ) ~ 393 10.1021/ma400686j
poly(vinyl methyl ether ) 251 10.1021/ma102121t
Hydroxymethyl-Functionalized Polyimide 523 10.1021/ma060372d
polyimide 440 10.1021/ma060372d
Polyimide 463 10.1021/ma060372d
poly(indene carbonate)s 423 10.1021/ma500112c
Poly(N-acryloylmorpholine) 423 10.1021/ma071710t
poly-N-[(2,2-dimethyl-1,3-dioxolane)methyl]acrylamide ~ 296 10.1021/ma901055t
Poly(dimethylsilane) 439 10.1021/ma070790y
polyurethanes 283 10.1021/ma401260d
poly(styrenesulfonate) 428 10.1021/ma9002566
Poly(vinyl alcohol ) 290 10.1021/ma0611826
Arene − Perfluoroarene Poly(phenylene ethynylenes ) 290 10.1021/ma062667x
Polyhydroxyalkanoate 235 10.1021/ma100294r
PMHPAC27 [Poly(5-methyl-5-(2-hydroxypropyl)aminocarbonyl-1,3-dioxan-2-one)] 332.6 10.1021/acs.macromol.5b01974
Diblock Copolymer, PMAC-b-PMBC 307 10.1021/acs.macromol.5b01974
poly(ferrocenylenedivinylene) 338 10.1021/ma071034v
poly(vinyl acetate ) 323 10.1021/ma4008187
poly(N-vinylimidazole) 448 10.1021/ma301712k
poly(l - lactic acid ) 318.4 10.1021/ma300288v
poly(ethylene terephthalate ) 353 10.1021/ma702554t
Polyurea 211 10.1021/ma8011009
Poly(phthalazinone ether)s 589 10.1021/ma0605651
Polystyrene ~ 373 10.1021/ma060352b
Poly(nitroxylstyrene)s 383 10.1021/ma0628578
Poly(d,l-lactide-block-ε-caprolactone) 213 10.1021/ma9010439
Poly(2,2,6,6-tetramethylpiperidin-1-oxyl-4-yl methacrylate ) 344 10.1021/ma702576z
Poly(n-butyl acrylate)-block-poly(acrylic acid ) 218 10.1021/ma0609580
poly(vinyl cinnamate ) 350 10.1021/ma070023z
Poly(n-butyl acrylate)−Spirooxazine 373 10.1021/ma052002f
poly(α-fluoroacrylate)s 413 10.1021/ma100506e
poly(hexafluoroisopropyl α,β-difluoroacrylate ) 371 10.1021/ma100506e
Poly(vinylidene fluoride ) 233 10.1021/ma061554a
Poly(ϵ-caprolactone) ~ 388 10.1021/ma800517k
2,5-Poly(3-[1-ethyl-2(2-(poly(N,N-dimethylaminoethyl methacrylate))]thiophene 293 10.1021/ma800777m
poly(methyl methacrylate ) ~ 388 10.1021/ma300291q
poly(ε-caprolactone) ~ 213 10.1021/ma300291q
Poly(1-oxy-2,2,6,6-tetramethylpiperidin-4-yl methacrylate ) 344 10.1021/ma1020159
poly(benzyl methacrylate ) 327 10.1021/ma900922d
Poly[biphenyl-4,4 ‘ -diylcarbonyl(6-methoxy-1,3-phenylene)[bis(trifluoromethyl)methylene](4-methoxy-1,3-phenylene)carbonyl ] ( P3 ) 491 10.1021/ma061319s
poly[[1,1 ‘ -biphenyl]-4,4 ‘ -diyl[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene] ] 528 10.1021/ma061319s
polycarbonate 378 10.1021/ma4015092
poly(allyl glycidyl ether ) 278 10.1021/ma401267w
poly(4-acetoxystyrene) ~ 403 10.1021/ma8009454
polystyrene 373 10.1021/ma8009454
atactic polystyrene ~ 373 10.1021/ma062423c
Thermoresponsive Poly(methacrylamide) 313.6 10.1021/ma300355k
poly(N-isopropylacrylamide) 313.6 10.1021/ma300355k
Poly(butylene-2,6-naphthalate) 314 10.1021/ma702383b
diacetylene-terminated polytetrahydrofuran 206.9 10.1021/ma9014577
polyimides > 523 10.1021/ma901392h
Poly(phthalazinone ether)s 513 10.1021/ma702039a
poly(aryl ether sulfone ) 496 10.1021/ma0713714
Poly[(CTFE-alt-VE)-co-(HFP-alt-VE)] 264 10.1021/ma900860u
polystyrene 382 10.1021/ma061839n
polynorbornenes > 613 10.1021/ma061215h
Polylactides 329 10.1021/ma060316c
poly(2-(4-vinylphenyl)pyridine) 434.4 10.1021/ma071349a
poly(arylene ether)s 351.4 10.1021/ma070013y
poly(tetramethyl glycolide ) 343 10.1021/ma102289w
Regioregular P3HT-b-PMMA Copolymers 399 10.1021/ma3008114
polyimide 358 10.1021/ma8022475
Poly(vinylphenol-b-4-vinylpyridine) 485 10.1021/ma061713q
polystyrene 373 10.1021/acs.macromol.5b02253
Polystyrene 345 10.1021/acs.macromol.5b02474
poly(ethynylstyrene) 426 10.1021/ma8007493
Poly(TMSpropargyloxystyrene) 321 10.1021/ma8007493
Poly(TBU-oxystyrene-b-4-(1′-adamantanyltriazolylmethyloxy)styrene) 378 10.1021/ma8007493
poly(propargyloxystyrene) 327 10.1021/ma8007493
Aliphatic Polycarbonate 267.4 10.1021/ma901791a
Poly(2-acrylamido-2-methyl-1-propanesulfonic acid ) 448 10.1021/ma800612t
poly(phenylquinoxaline) 643 10.1021/ma062259t
sulfonated polyimide > 523 10.1021/ma501097k
sulfonated polysulfones ~ 463 10.1021/ma501097k
Polysiloxane 154 10.1021/ma900984n
poly(ethylene oxide)−poly(butadiene) > 263 10.1021/ma702322b
polyurethanes.11 413 10.1021/ma0608875
polystyrene ~ 373 10.1021/ma0617421
poly(ethyl acrylate ) 251 10.1021/ma300644v
poly(methyl methacrylate ) 373 10.1021/ma300644v
Poly(l - lactic acid ) ~ 333 10.1021/ma301482j
polycarbonate 423 10.1021/ma300730y
polystyrene 373 10.1021/ma052625t
poly(oxyethylene) 290 10.1021/ma800327c
Poly(IEVE-alt-CTFE) ( II ) 312 10.1021/ma400239f
poly(CTFE-alt-IEVE)-g-4(5)hydroxyethylimidazole 323 10.1021/ma400239f
poly(1,3-cyclohexadiene carbonate ) 362 10.1021/acs.macromol.5b00172
polycarbonates 303 10.1021/acs.macromol.5b02108
Poly(N-arylcarbazol-2,7-ylene) > 423 10.1021/ma061764n
Poly(acrylamide) 438 10.1021/acs.macromol.5b02178
poly(acrylic acid ) 378 10.1021/acs.macromol.5b02178
Poly(ethylene glycol ) ~ 298 10.1021/acs.macromol.5b02178
Polystyrene 370 10.1021/ma061659d
polyisobutylene 193 10.1021/ma801465r
poly(α-methylstyrene) 193 10.1021/ma801465r
1,4-polyisoprene ~ 217 10.1021/acs.macromol.5b02642
1,4-polybutadiene ~ 183 10.1021/acs.macromol.5b02642
poly(α-methylstyrene) ~ 446 10.1021/acs.macromol.5b02642
poly(α-methyl-p-methylstyrene) ~ 456 10.1021/acs.macromol.5b02642
poly(tert-butylstyrene) ~ 403 10.1021/acs.macromol.5b02642
poly(p-adamantylstyrene) ~ 476 10.1021/acs.macromol.5b02642
poly(vinylcyclohexane) ~ 420 10.1021/acs.macromol.5b02642
Poly(bismethoxyphosphazene) 202.2 10.1021/ma071429e
Poly(glycolide-block-rac-lactide) 318.5 10.1021/ma402174y
Polystyrene 370 10.1021/ma071759z
polyferrocenylsilanes 306 10.1021/ma9018608
poly(vinyl methyl ether ) 242 10.1021/ma401052x
poly(MEBIm-TFSI) 280 10.1021/ma400562a
poly(AEBIm-TFSI) 266 10.1021/ma400562a
Poly(lactic acid ) ~ 331 10.1021/ma302081e
Poly(pyrrole) 343 10.1021/ma9001897
Polylactide ~ 316 10.1021/ma071626d
poly(4-vinylpyridine) 415 10.1021/acs.macromol.5b02670
poly[2-(methacryloyloxy)ethyl]dimethyl(3-sulfopropyl)ammonium hydroxide 325 10.1021/ma800625y
Poly(methyl methacrylate ) ~ 393 10.1021/ma702714c
poly(ethylene terephthalate ) 346 10.1021/ma7027616
poly(ethylene terephthalate ) 348 10.1021/ma9005318
poly(3-(4′-(3′′,7′′-dimethyloctoxy)-3′-pyridinyl)thiophene) 293 10.1021/ma102661s
polydimethylsiloxane 146 10.1021/ma8006015
poly(ε-caprolactone) 213 10.1021/ma9000622
polydimethylsiloxane 150 10.1021/ma070671i
Poly(MDO-co-MMA-co-DMAEMA) 324 10.1021/ma802615f
poly(p-methylenetriphenylamine) 431 10.1021/ma800127v
poly(BC-co-BS) 233 10.1021/ma7028709
Poly(styrene-b-dimethylsiloxane) 150 10.1021/ma062779o
poly(1,3-adamantane)s 412 10.1021/ma300395s
Poly(methyl methacrylate ) 383 10.1021/ma800237x
polyethylene 197 10.1021/ma800616h
PG − PPO − PG Copolymers 291 10.1021/ma801086b
poly(acrylic acid ) 379 10.1021/ma070893g
Poly(VI-co-MAA) 336 10.1021/ma402424f
poly(l-lactide) ~ 320 10.1021/ma8024943
Poly((R,S)-3-methyl-1-pentene) 316 10.1021/acs.macromol.5b00921
Poly(p-phenylenevinylene)s 308 10.1021/ma0628836
poly(methyl methacrylate ) 350 10.1021/ma101217y
Fluorinated Poly(arylene alkylene ether)s 318 10.1021/ma071669u
poly[(R)-3-hydroxyvalerate ) 256 10.1021/ma801653p
poly(styrene-b-methyl methacrylate-b-styrene ) 249 10.1021/acs.macromol.5b00882
poly(l - lactic acid ) 333 10.1021/ma3010982
Poly((±)endo,exo-N,N′-diphenylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxamide) 479 10.1021/ma802126y